Interdiffusion and Internal Stress Effects in Closed Geometry
DOI:
https://doi.org/10.62721/diffusion-fundamentals.39.1276Keywords:
DiffusionAbstract
This study examines how cylindrical geometry influences interdiffusion and stress development during the formation of ZnAl₂O₄ in nanoscale Pt/Al₂O₃/ZnO structures. Double-layered nanopillars with different diameters were annealed to induce reactive diffusion, and STEM imaging was used to measure intermetallic growth. Smaller pillars exhibited thinner ZnAl₂O₄ layers due to stronger diffusion-inhibiting stresses that cannot relax in closed geometries. At longer times parabolic growth behavior was observed. These results show that curvature-dependent stress fields play a key role in regulating diffusion kinetics at the nanoscale.
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Copyright (c) 2025 Barbara Sárközi, Gergő Vecsei, Zoltán Erdélyi, Csaba Cserháti

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